I followed everything in the course but when I tried to assign an individual materials per face, the image below occurs:
I really don’t know what’s happening and all my set-up are in default. 
Can someone help me regarding this one?
Maybe restart with a new cube?
In object mode add two materials to the cube.
Then in edit mode select a single face and assign a material to it.
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Weird effect be good to know how you managed it!
Still simplest to start over as Fed Pete says.
I tried restarting Blender with new cube and Blender itself. I also tried adding two materials during object mode and produced the same output. Unfortunately my solution is to uninstall blender and install the latest version one. From 2.83 to 2.91.
Still very strange!
Did you created a new Blender startup file? Where the cube has a different structure?
Can you upload the .blend file?
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As said this is very strange as if it works in 2.91 it should work in 2.83 as the LTS version.
There will be quite a few changes in 2.91 as its still going through development but if you get stuck pop a question up or join discord 
If you can upload the blend file that would be great
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